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The Effect of Peripheral Circuits on the Total p-Electron Energies of Cyclacenes

Within the framework of the Hückel molecular orbital theory, certain linear models are developed to express the contribution of peripheral circuits of cyclacenes into their total p-electron energies, which explain why cyclacenes exhibit the cryptoannulenic behavior as their peripheral circuits which are annulenic in character.

Anahtar Kelimeler:

Turk. J. Chem., 24, (2000), 217-222. Full text: pdf Other articles published in the same issue: Turk. J. Chem., vol.24, iss.3.

The Effect of Peripheral Circuits on the Total p-Electron Energies of Cyclacenes

Within the framework of the Hückel molecular orbital theory, certain linear models are developed to express the contribution of peripheral circuits of cyclacenes into their total p-electron energies, which explain why cyclacenes exhibit the cryptoannulenic behavior as their peripheral circuits which are annulenic in character.

Keywords:

Turk. J. Chem., 24, (2000), 217-222. Full text: pdf Other articles published in the same issue: Turk. J. Chem., vol.24, iss.3.,

Turkish Journal of Chemistry-Cover

ISSN: 1300-0527
Yayın Aralığı: Yılda 6 Sayı
Yayıncı: TÜBİTAK

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