Synthesis, characterization, and biological activity of coordination polymers derived from pyromellitic dianhydride

A new ligand, 2,5-bis(furan-2-ylmethylcarbamoyl)terephthalic acid (BFMTA), was synthesized using 1,2,4,5-benzenetetracarboxylic dianhydride (pyromellitic dianhydride-PMDA) with furan-2-ylmethanamine (2-furfurylamine). New coordination polymers of the ligand (BFMTA) were also prepared using transition metal ions Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) metal salts. The coordination polymers and ligand were characterized by physico-chemical characteristics, magnetic susceptibilities, spectroscopic investigations, and thermogravimetry. Antimicrobial activity was tested using the agar-plate method against various strains of bacteria and spores of fungi. The results showed significantly higher antimicrobial activity of coordination polymers compared to the ligand.

Synthesis, characterization, and biological activity of coordination polymers derived from pyromellitic dianhydride

A new ligand, 2,5-bis(furan-2-ylmethylcarbamoyl)terephthalic acid (BFMTA), was synthesized using 1,2,4,5-benzenetetracarboxylic dianhydride (pyromellitic dianhydride-PMDA) with furan-2-ylmethanamine (2-furfurylamine). New coordination polymers of the ligand (BFMTA) were also prepared using transition metal ions Mn(II), Fe(II), Co(II), Ni(II), Cu(II), and Zn(II) metal salts. The coordination polymers and ligand were characterized by physico-chemical characteristics, magnetic susceptibilities, spectroscopic investigations, and thermogravimetry. Antimicrobial activity was tested using the agar-plate method against various strains of bacteria and spores of fungi. The results showed significantly higher antimicrobial activity of coordination polymers compared to the ligand.

___

  • Dave, P. N.; Patel, N. N. Mater. Sci. Appl. 2011, 2, 771–776.
  • Tamaki, R.; Choi, J.; Laine, R. M. Chem. Mater. 2003, 15, 793–797.
  • Ueda, M.; Nakayama, T. Macromolecules 1996, 29, 6427–6431.
  • Yan, L.; Park, C.; Ounaies, Z.; Irene, E. A. Polymer. 2006, 47, 2822–2829.
  • Ramkumar, S. G.; Ramakrishnan, S. J. Chem. Sci. 2008, 120, 187–194.
  • Masahiro, T.; Takahiro, H.; Hiroyuki, O. Tetrahedron Lett. 2007, 48, 1553–1557.
  • Matsuura, T.; Hasuda, Y.; Nishi, S.; Yamada, N. Macromolecules 1991, 24, 5001–5005.
  • Patel, Y. S.; Patel, H. S.; Srinivasulu, B. Int. J. Plast. Technol. 2012, 16, 117–124.
  • Patel, Y. S.; Patel, H. S. Elixir Appl. Chem. 2012, 44, 7238–7242.
  • Vanparia, S. F.; Patel, T. S.; Sojitra, N. A.; Jagani, C. L.; Dixit, B. C.; Patel, P. S.; Dixit, R. B. Acta Chim. Slov. 2010, 57, 660–667.
  • Vogel, A. I. A Textbook of Quantitative Inorganic Analysis, 3rd Ed., Longman: London, p.433, 1961. Jeffery, G. H.; Bassett, J.; Mentham, J.; Denney, R.C. Vogel’s Textbook of Quantitative Inorganic Analysis, fifth ed. Longman: Harlow, 1989.
  • Chatterjee, S. K.; Gupta, N. D. J. Polym. Sci., Polym. Chem. Ed. 1973, 11, 1261–1270.
  • Silverstein, R. M.; Webste, F. X. Spectrometric Identification of Organic Compounds. 6th Ed.; John Wiley & Sons, Inc: New York, 2004.
  • Panchal, P. K.; Pansuriya, P. B.; Patel, M. N. J. Enz. Inhib. Med. Chem. 2006, 21, 453–458.
  • Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Ed.; Wiley: New York, 19 Lever, A. B. P. Inorganic Electronic Spectroscopy ; 2nd Ed; Elsevier: Amsterdam, 1984.
  • Malik, A.; Parveen, S.; Ahmad, T. Bioinorg. Chem. Appl. 2012, 10, 1155–1162.
  • Soliman, E. M.; El-Shabasy, M. J. Mater. Sci. 1994, 29, 4505–4509.
  • Lewis, J.; Wilkins, R. S. Modern Coordination Chemistry. Interscience: New York, p. 290, 1960.
  • Papplardo, R. J. Chem. Phys. 1960, 33, 613–614.
Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

Synthesis, characterization, and fluorescence study of phthalhydrazidylazo derivative of an unsaturated diketone and its metal complexes

Radhika PALLIKKAVIL, Muhammed Basheer UMMATHUR, Krishnannair KRISHNANKUTTY

Synthesis of new N-[3-(Benzo[d]thiazol-2-yl)-4-methylthiazol-2(3H)-ylidene] substituted benzamides

Aamer SAEED, Hummera RAFIQUE

Simple and convenient preparation of novel 6,8-disubstituted quinoline derivatives and their promising anticancer activities

Salih ÖKTEN, Osman ÇAKMAK, Ramazan ERENLER, Önem YÜCE, Şaban TEKİN

Synthesis of tetrakis(carboxyphenyl)porphyrin coated paramagnetic iron oxide nanoparticles via amino acid for photodegradation of methylene blue

Rahmatolah RAHIMI, Azadeh TADJARODI, Mina IMANI, Mahboubeh RABBANI, Samaneh Safalou MOGHADDAM, Hamed KERDARI

Synthesis, characterization, and DFT calculation of a Pd(II) Schiff base complex

Alireza AKBARI, Zahra ALINIA

Comparative study of microwave-assisted and conventional synthesis of ibuprofen-based acyl hydrazone derivatives

Ayşe Uzgören BARAN

Syntheses, characterization, and antibacterial study of titanium complexes

Raj KAUSHAL, Nitesh KUMAR, Pamita AWASTHI, Kiran NEHRA

Sesquiterpene hydrocarbons of the essential oil of Actinolema macrolema Boiss

Betül DEMİRCİ, Gülden Koltuksuz YASDIKCIOĞLU, Kemal Hüsnü Can BAŞER

Electrochemical determination of Sudan IV in food samples by using graphene-modified glassy carbon electrodes

Meifeng CHEN, Xinying MA, Xia LI

Biodegradability of degradable mulching film in a laboratory-controlled composting test

Xuemei ZHANG, Yaxi HUANG, Deqiang LI, Zicheng WEN, Baoxun SUI, Zhiyong LIU