Synthesis and characterization of copper(II), nickel(II), cadmium(II), cobalt(II), complexes with 2-benzoyl-3-hydroxy-1-naphthylamino-3-phenyl-2-propen-1-on

Synthesis and characterization of copper(II), nickel(II), cadmium(II), cobalt(II), complexes with 2-benzoyl-3-hydroxy-1-naphthylamino-3-phenyl-2-propen-1-on

Cu(II), Ni(II), Co(II), Zn(II) and Cd(II) complexes of 2-Benzoyl-3-hydroxy-1-naphthylamino-3-phenyl-2-propen-1-on, which is a derivative of carboxamide, were prepared and characterized by elemental, spectral and magnetic methods. Based on the analytical results, electronic and infrared spectral data and magnetic susceptibility measurements, suitable structures have been proposed. The formation of the complexes in solution was investigated conductometrically. 2-Benzoyl-3-hydroxy-1-naphthylamino-3-phenyl-2-propen-1-on was found to be a bidentate ligand coordinating through enolic oxygen and amide nitrogen. The complexes of Co(II) and Ni(II) are proposed to have an octahedral structure, while Cd(II), Cu(II) and Zn(II) are suggested to possess a square-planar environment in the complexes.

___

Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
Sayıdaki Diğer Makaleler

A Novel Technique for Silver Extraction from Silver Sulphide Ore

S. AYATA, H. YILDIRAN

Adsorption of Some Textile Dyes by Hexadecyltrimethylammonium Bentonite

Özlem CEYHAN, Demet BAYBAŞ

Reaction mechanism and kinetics of aqueous solutions of 2-amino-2 methyl-1,3- propanediol and carbonyl sulphide

E. ALPER

Structural studies of water-soluble beta-brominated manganese porphyrins: Stabilities of MnTDCSPPBr8 and MnTSPPBr8 as homogeneous and supported reagents toward hydrogen peroxide and sodium hypochlorite

Hayrettin TÜRK, Hüseyin BERBER

Optimization of Process Parameters for Reactive Lactic Acid Extraction

E. KAHYA, E. BAYRAKTAR, Ü. MEHMETOĞLU

The Composition of Essential Oils From Two Varieties of Sideritis erythrantha var. erythrantha and var. cedretorum

Nurhayat TABANCA, Neşe KIRIMER, K. Hüsnü Can BAŞER

Synthesis and characterization of copper(II), nickel(II), cadmium(II), cobalt(II), complexes with 2-benzoyl-3-hydroxy-1-naphthylamino-3-phenyl-2-propen-1-on

Mehmet SÖNMEZ

Accumulation of Heavy Metals in Freshwater Organisms: Assessment of Toxic Interactions

Neylan DİRİLGEN

Photochemically-Induced Fluorescence Properties and Determination of Flufenamic Acid, a Non-Steroidal Anti-Inflammatory Drug, in Urine and Pharmaceutical Preparation

Leila BETTAIEB, Jean-Jacques AARON

Usefulness of a Technique Based on Negative Corona Discharge for the Degradation of Selected, Condensed PAHs: Application to the Oxidation of Anthracene and Similar Structures

D. TESSIER, C. OGUIC, J. J. AARON, J. PINART