Peter MAYER, Abubak'r ABRAHAMS, Thomas GERBER, Eric HOSTEN

6229

Oxorhenium(V)-mediated synthesis and structures of oxypyridinium-ammonium zwitterions

Oxorhenium(V)-mediated synthesis and structures of oxypyridinium-ammonium zwitterions

Treatment of N,N -bis(2-hydroxybenzyl)-2-(2-aminoethyl)dimethylamine (H2 had) with trans-[ReO2 (py) 4 ]I in acetone affords the iodide salts of the oxypyridinium-ammonium zwitterions N1 -(2-hydroxybenzyl)- N2 ,N2 -dimethyl-N1 -((2-oxypyridinium)-1-methyl)ethane-1,2-diamine [Hhpd]+ and N2 ,N2 -dimethyl-N1 - bis((2-oxypyridinium)-1-methyl)ethane-1,2-diamine [dod]+ . The products were characterized by X-ray structure analysis, and NMR and IR spectroscopy.
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Turkish Journal of Chemistry-Cover
  • ISSN: 1300-0527
  • Yayın Aralığı: Yılda 6 Sayı
  • Yayıncı: TÜBİTAK
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Reactions of the solvent-stabilized compound $[MoOCI_2(THF)_2]$ with aromatic nitrogen donor ligands: spectroscopic characterization and semiempirical AM1 calculations

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Oxorhenium(V)-mediated synthesis and structures of oxypyridinium-ammonium zwitterions

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