Nuran AY, Gökçe Mehmet AY, Yapıncak GÖNCÜ

Environmentally friendly material: Hexagonal boron nitride

Importance of environmental issues has increased every year and several global summits were held on this subject. As a result, research efforts are focused on environmentally friendly materials, reducing energy usage and emissions. Hexagonal boron nitride (hBN) with superior lubrication is an environmentally friendly material. It’s structure of strong bonds between atoms in layers with weak Van Der Walls bonds between layers gives low friction. Also, hBN is an inorganic artificial material with high heat shock resistance, heat conduction, electrical insulation and chemical stability. These properties makes hBN suitable for various applications. In this study, friction and wear behaviors of products containing hBN were reviewed, in order to see effects for sustainable environment

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[1] http://www. un.ora/apps/news/storv. asp?NewsID=51526#.VrG8IU1f0uU
[2] Apelian D., Looking beyond the last 50 years: The future of materials science and engineering, JOM, 65-75, 2007.
[3] Rödel J., Kounga A. B. D., Weissenberger-Eibl E.,
Koch D., Bierwisch A., Rossner W., Hoffmann M. J., Danzer R., Schneider G., Development of roadmap for advanced ceramics: 2010-2025, Journal of ECERS, 1549-1560, 2009.
http:/Iwww.nanowerk.com/spotliqht/spotid=16047th Lansdown A. R., Lubrication and Lubricant Selection Practical Guide, Third Edition, London and Bury St Edmunds, UK, 2004.
Tung 8. C., McMillan M. L., Automotive tribology overview of currrent advances and challenges for The Future, Tribology International, 37, 517-536, 2004.
Booser E. R., CRC Handbook of Lubrication, Theory and Practice of Tribology, Volume ||: Theory and Design, CRC press, 1988.
http:/lenerav.qov/sites/prod/üles/2013/11/f4/nanoı0arWadi2016 Kenneth H., Andersson P., Erdemir A., Global energy consumption due to friction in passenger cars, Tribology International, 47, 221—234, 2012.
Lansdown A. R., Molybdenum Disulphide Lubrication, Swansea UK, 1999.
Mang T. and Dresel W., Lubricants and Lubrication Second, Completely Revised and Extended Edition, Weinheim Almanya, 2007.
Sotres J., Arnebrant T., Experimental investigations of biological lubrication at the nanoscale: The cases of synovial joints and the oral cavity, Lubricants, 1, 102-131, 2013.
Jamaludin N., Mba D., Bannister R. H., Monitoring the Iubricant condition in low-speed rolling element bearing using high frequency stress waves, Proceedings of the Institution of Mechanical Engineers Part E-Journal of Process Mechanical Engineering, 216 (2), 73-88, 2002.
Xu J., Wang F., Liu Z. L., Investigation of the tribology behaviors of auto-restoration additive under heavy loading conditions, Surface Review and Letters 14 (2), 329-334, 2007.
Benz M., Chen N. H., Israelachvili J., Lubrication and wear properties of grafted polyelectrolytes, hyaluronan and hylan, measured in the surface forces apparatus, Journal of Biomedical Materials Research Part A, 71A (1), 6-15, 2004.
Kumar P., Oka M., Toguchida J., Kobayashi M., Uchida E., Nakamura T., and Tanaka K., Role of uppermost superficial surface layer of articular cartilage in the lubrication mechanism of joints, Journal ofAnatomy, 199, 241-250, 2001.
Oates K. M. N., Krause W. E., Jones R. L., and Colby R. H., Rheopexy of synovial fluid and protein aggregation, Journal of the Royal Society Interface, (6), 167- 174, 2006.
Jiang B. C. and Liu P. P., Natural lubrication and wear of textile spinning rings, Tribology Transactions, 34 (3), 369—374, 1991.
Hu Y. Z. and Granick S., Microscopic study of thin film lubrication and its contributions to macroscopic tribology, Tribology Letters, (1), 81-88, 1998.
Liang J., Investigation of synthetic and natural lubricants, PhD Thesis, NCSU USA, 2008.
Pirro D. M. and Wessol A. A., Lubrication Fundamentals Second Edition Revised and Expanded, New York, 2001.
Totten G. E., Handbook of Lubrication and Tribology Volume Second Edition, USA, 1-9, 2006.
Ludema K. C., Friction, Wear, Lubrication, USA, 1996.
Scharf T. W. and Prasad S. V., Solid lubricants: review, J. Mater Sci, 48, 511—531, 2013.
Prabhu T. R., Effects of solid lubricants, load, and sliding speed on the tribological behavior of silica reinforced composites using design of experiments, Materials and Design, 77, 149—160, 2015.
Cho D. H., Kim J. S., Kwon S. H., Lee C., Lee Y. Z., Wear, 302, 981—986, 2013.
Kumari S., Sharma O. P., Gusain R., Mungse H. P., Kukrety A. K., Kumar N., Sugimura H., Khatri O. P., AIkyl-chain-graftedh hexagonal boron nitride nanoplateIets as oil-dispersible additives for friction and wear reduction, ACS Appl. Mater. Interfaces, 7, 3708—3716, 2015.
Deepika, Li, L. H., Glushenkov A. M., Hait S. K., Hodgson P., Chen Y., High-efficient production of boron nitride nanosheets via an optimized ball milling process for lubrication in oil, Conferance Proceeding, ACSMS2014, Scientific Reports, 4, 7288, 1-6, 2014.
Haubner R., Wilhelm M., Weissenbacher R., Lux B., Boron nitrides—properties synthesis and applications, Springer-Verlag, Berlin, 2002.
Paine R. T., Narula C. K., Synthetic routes to boron nitride, Chem. Rev. 90, 73—91, 1990.
Kempfer L., The many faces of boron nitride, Mater. Eng. 107, 41—44, 1990.
Rudolph S., Materials review: Boron nitride, American Ceramic Society Bulletin, August, 81 (8), 34-35, 2002.
Naftaly M., Leist J., Dudley R., Investigation of ceramic boron nitride by terahertz time-domain spectroscopy, Journal of the European Ceramic Society, 30, 2691- 2697, 2010.
V. Siklitsky, Boron Nitride, http:/lwww.ioffe.rssi.ru/SVA/ NŞMLŞemiçgndlBNzindex.html, 2010. [35]
Kimura Y., Wakabayashi T., Okada K., Wada T., Nishikawa H., Boron nitride as lubricant additive, Wear, 232, 199-206, 1999.
Engler M., Lesniak C., Damasch R., Ruisinger B., Eichler J., Hexagonal boron nitride (hBN)-applications from metallurgy to cosmetics, ACM of German Ceramic Society, Dresden, 2007.
http://www.substech.com/dokuwiki/doku.phb?- id=boron nitride as solid lubricant Greim J., Schwetz K. A., Boron carbide, boron nitride and metal borides, Ullmann’s Encyclopedia of Industrial Chemistry, Weinheim, 2005. http://www.boronmax.com/tr raporlar.a_sg, 2016.
Abdullah M. I. H. C., Abdollah M. F. B., Amiruddin H., Nuri N. R. M, Optimized nanolubricant for friction reduction, 40'h Leeds-Lyon Symposium on Tribology Tribochemistry Forum, 54, 2013.
Reeves C. J, Menezes P. J, Lovell M. L., Jen T. C., The size effect of boron nitride particles on the tribological performance of biolubricants for energy conservation and sustainability, Tribol. Lett., 51, 437—452, 2013.
Çelik O. N., Ay N., Göncü Y., Effect of nano hexagonal boron nitride Iubricant additives on the friction and wear properties of AISI 4140 steel, Particulate Science and Technology, 31, 501—506, 2013.
Abdullah M. I. H. C., Abdollah M. F. B., Amiruddin H., Tamaldin N., Nuri N. R. M., Effect of hBN/AI2O3 nanoparticle additives on the tribological performance of engine oil Jurnal Teknologi, 66 (3), 1—6, 2014.
Abdollah M. F. B., Abdullah M. I. H. C., Amiruddin H., Tamaldin N., Rashid M. N. N., The hBN nanoparticles as an effective additive in engine oil to enhance the durability and performance of small diesel engine, 41'h Leeds-Lyon Symposium on Tribology, United Kingdom, 2014.
Abdullah M. |. H. C., Abdollah M. F. B., Amiruddin H., Nuri N. R. M, The potential of hBN nanoparticles as friction modifier and antiwear additive in engine oil, Mechanics Industry 17, 104, 2016.
Wan Q., Jina Y., Suna P., Dinga Y., Tribological behaviour of Iubricant oil containing boron nitride Nanoparticles, Procedia Engineering, 102, 1038—1045, 2015.
Baş H., Karabacak Y. E., Investigation of the Effects of Boron Additives on the Performance of Engine Oil, Tribology Transactions, 57, 740-748, 2014.
Podgornik B, Kosec T., Kocijan A., Donik C., Tribological behavior and lubrication performance of hexagonal boron nitride (h-BN) as replacement for graphite in aluminium forming, Tribology International, 81, 267—275, 2015.
[49] Wen M. Y., Guo P., Hui J. D., Hui Z. M., Geng F., The ef— [50] Greco A., Mistry K., Sista V., Eryilmaz O., Erdemir A., fect of additives on tribological behaviours in polyurea Friction and wear behaviour of boron based surface grease, Materials Research Innovations, 19 (5), 596- treatment and nano-particle lubricant additives for wind 599, 2015. turbine gearbox applications, Wear, 271, 1754—1760, 2011.